Advertisement

Effect of high pressure on the rate constant of the Diels-Alder reaction between furan and maleic anhydride

  • V. M. Zhulin
  • M. V. Kel'tseva
  • V. S. Bogdanov
  • Yu. D. Koreshkov
  • E. B. Kabotyanskaya
Physical Chemistry
  • 67 Downloads

Abstract

The effect of high pressure (up to 700 MPa) on the rate of the Diels-Alder reaction between furan and maleic anhydride has been investigated in deuterated acetone at 20‡C. The volume effect of the reaction at atmospheric pressure is found to be δV0=−28.0 cm3/mole. The rate constants for the formation, decomposition and isomerization of the products have been found by numerical integration. The volume of activation δV in the pressure range studied has been determined from the observed dependence of log k upon P by spline approximation and was found to be −30.5 cm3/mole at atmospheric pressure, close to the volume change in the reaction, which is consistent with the assumption of a conjugated cyclic transition state.

Keywords

Acetone High Pressure Transition State Anhydride Volume Change 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    V. M. Zhulin, V. S. Bogdanov, M. V. Kel'tseva, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 11, 2510 (1989).Google Scholar
  2. 2.
    V. M. Zhulin, G. V. Ostval'd, V. S. Bogdanov, et al., Dokl. Akad. Nauk SSSR,302, No. 6, 1408 (1988).Google Scholar
  3. 3.
    R. A. Grieger and C. A. Eckert, Am. Inst. Chem. J.,16, No. 5, 766 (1970).Google Scholar
  4. 4.
    B. S. El'yanov and M. G. Gonikberg, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, No. 5, 934 (1961).Google Scholar

Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • V. M. Zhulin
    • 1
  • M. V. Kel'tseva
    • 1
  • V. S. Bogdanov
    • 1
  • Yu. D. Koreshkov
    • 1
  • E. B. Kabotyanskaya
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

Personalised recommendations