Abstract
Thermal changes in Cu2B10H10 have been studied over the temperature range 25–800‡C using DTA, gas-volume, IR-spectroscopic, and x-ray phase analytical methods. Decomposition of the salt starts at 290‡C and is accompanied by formation of amorphous and crystalline phases of CuB24, Cu, and Bam. A crystalline copper phase starts to form at 290‡C.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 503–506, March, 1990.
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Volkov, V.V., Yur'ev, G.S., Solomatina, L.Y. et al. Thermal changes in decahydro-closo-decaborate(2-)copper(I) Cu2B10H10 and the nature of copper borides. Russ Chem Bull 39, 435–438 (1990). https://doi.org/10.1007/BF00959553
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DOI: https://doi.org/10.1007/BF00959553