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1-phenyl-4,4-dimethyl-1,4-phosphasilacyclohexane and its selenide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    1-Phenyl-4,4-dimethyl-1,4-phosphasilacyclohexane was formed upon the photochemical addition of phenylphosphine to dimethyl(divinyl)silane and gave 1-phenyl-4,4-dimethyl-1-seleno-1,4-phosphasilacyclohexane upon reaction with elemental selenium.

  2. 2.

    NMR spectroscopy indicated that 1-phenyl-4,4-dimethyl-1,4-phosphasilacyclohexane and 1-phenyl-4,4-dimethyl-1-seleno-1,4-phosphasilacyclohexane exist in the chair conformation with predominance of the conformer with axial orientation of the unshared electron pair of the phosphorus atom.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    M. G. Voronkov, N. M. Kudyakov, A. I. Albanov & V. Yu. Vitkovskii

Authors
  1. M. G. Voronkov
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  2. N. M. Kudyakov
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  3. A. I. Albanov
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  4. V. Yu. Vitkovskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 451–453, February, 1987.

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Voronkov, M.G., Kudyakov, N.M., Albanov, A.I. et al. 1-phenyl-4,4-dimethyl-1,4-phosphasilacyclohexane and its selenide. Russ Chem Bull 36, 409–411 (1987). https://doi.org/10.1007/BF00959395

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  • DOI: https://doi.org/10.1007/BF00959395

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