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Synthesis and properties of arenetetracobalt noncarbonyl clusters

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reactions of Co2(CO)8 with arenes in hexane gave arenecarbonyl clusters, ArenCo4(CO)9 including products with functional substituents in the side chain. The reactions of these products with nucleophiles and electrophiles were studied. The photochemical replacement of CO by PPh3 gave Me3C6H3Co4(CO)8PPh3 and the chemical properties of this product were studied.

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Literature cited

  1. I. U. Khand, G. R. Knox, P. L. Pauson, and W. E. Watts, J. Chem. Soc., Perkin Trans, 1, 975 (1973).

    Google Scholar 

  2. P. H. Bird and A. R. Fraser, J. Organometall. Chem.,73, 103 (1974).

    Google Scholar 

  3. A. Sisak, C. Sisak, F. Ungvary, G. Palyi, and L. Marko, J. Organometall. Chem.,90, 77 (1975).

    Google Scholar 

  4. V. S. Kaganovich, Abstracts of the Fourth European Conference on Organometallic Chemistry [in Russian], Riga (1985), p. 41.

  5. R. Kerber and D. Entholt, J. Am. Chem. Soc.,95, 2927 (1973).

    Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. S. Kaganovich & M. I. Rybinskaya

Authors
  1. V. S. Kaganovich
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  2. M. I. Rybinskaya
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 441–444, February, 1987.

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Kaganovich, V.S., Rybinskaya, M.I. Synthesis and properties of arenetetracobalt noncarbonyl clusters. Russ Chem Bull 36, 400–403 (1987). https://doi.org/10.1007/BF00959392

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  • DOI: https://doi.org/10.1007/BF00959392

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