Conclusions
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1.
It was shown that the thermally stable (to 300–400°C) transition metal glycolates, glycerates, and pinacolates could be obtained from bisarenyl, cyclopentadienyl, and carbonyl metal compounds by reaction with polymeric alcohols.
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2.
At 150–180°C monomeric compounds are formed; these are converted to polymeric products above 200°C.
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3.
When two glycolates react with various metals or when glycolates react with organometallic compounds, new, mixed complexes of a polymeric nature are obtained.
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A. M. Slushkov, V. I. Petrov, and G. A. Domrachev, Izv. Akad. Nauk SSSR, Ser. Khim., 1413 (1985).
K. G. Kochetikhina, G. A. Domrachev, and G. A. Razuvaev, Zh. Obshch; Khim.,39, 1108 (1969).
R. C. Mehrotra and J. Sigh, J. Inorg. Chem.,23, 1046 (1984).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 427–430, February, 1987.
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Slushkov, A.M., Petrov, B.I. & Domrachev, G.A. Reaction of bisarenyl, cyclopentadienyl, and carbonyl transition metal compounds with polyhydric alcohols. Russ Chem Bull 36, 385–388 (1987). https://doi.org/10.1007/BF00959388
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DOI: https://doi.org/10.1007/BF00959388