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Joint catalytic activation of CO2 and NH2 in reaction with butadiene under the action of palladium complexes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The possibility of joint catalytic activation of small molecules (CO2 and NH3) has been demonstrated in their reaction with butadiene with the participation of palladium complexes, the products being mono- and bis-(2,7-octadienyl)formamides.

  2. 2.

    It has been found that 2-pyrrolidone can take part in a telomerization reaction with butadiene in solutions containing palladium complexes, ammonia and carbon dioxide with the formation of N-2,7-octadienylpyrrolidone.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch of the Academy of Sciences of the USSR, Ufa

    U. M. Dzhemilev, R. V. Kunakova & V. V. Sidorova

Authors
  1. U. M. Dzhemilev
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  2. R. V. Kunakova
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  3. V. V. Sidorova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 403–405, February, 1987.

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Dzhemilev, U.M., Kunakova, R.V. & Sidorova, V.V. Joint catalytic activation of CO2 and NH2 in reaction with butadiene under the action of palladium complexes. Russ Chem Bull 36, 362–364 (1987). https://doi.org/10.1007/BF00959382

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  • DOI: https://doi.org/10.1007/BF00959382

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