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Selective carbalumination of monosubstituted acetylenes by aluminocuprate reagents

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The authors thank L. M. Khalilov, A. A. Panasenko, and A. A. Fatykhov for obtaining and discussing the spectra.

It has been shown for the first time to be possible to use for synthetic purposes the carbometallation of monosubstituted acetylenes by the aluminocuprate reagents R3Al-CuBr, and a study has been carried out of its chemo- and regioselectivity.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 397–403, February, 1987.

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Kuchin, A.V., Tolstikov, G.A. & Andreeva, N.I. Selective carbalumination of monosubstituted acetylenes by aluminocuprate reagents. Russ Chem Bull 36, 356–361 (1987). https://doi.org/10.1007/BF00959381

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  • DOI: https://doi.org/10.1007/BF00959381

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