Conclusions
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1.
An x-ray diffraction structural analysis gave the structure of the first complex of pentacoordinated Pt(II) with a free radical o-semiquinone ligand.
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2.
The trigonal bipyramidal geometry of the complex determined by ESR spectroscopy is in good accord with the x-ray diffraction structural analysis data.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 341–343, February, 1987.
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Saf'yanov, Y.N., Abakumov, G.A., Cherkasov, V.K. et al. Crystal and molecular structure of (triphenylphosphine) (2-methoxycycloocten-5-yl)(3,6-di-tert-butyl-1,2-benzosemiquinone)platinum(II), C41H50O3PPt. Russ Chem Bull 36, 301–303 (1987). https://doi.org/10.1007/BF00959368
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DOI: https://doi.org/10.1007/BF00959368