Conclusions
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1.
Quantitative dependences of the charge values at S and Cl atoms on their Kα shifts have been found. Values of q(S) and q(Cl) were determined for a variety of aryl alkyl sulfides and sulfones.
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2.
In contrast to the aryl alkyl sulfides, in the respective slufones the charge at the S atom stays practically constant for any substitution in the alkyl or aryl segments.
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3.
In p-chlorosubstituted aryl alkyl sulfides and sulfones the charge values at the Cl atom varies over quite a narrow range, ∼0.1 e; the dependence of q(Cl) on the electronic properties of the p-substituent is complicated.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 336–340, February, 1987.
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Dolenko, G.N., Kondratenko, N.V., Popov, V.I. et al. Determination of the charge state of heteroatoms in organic compounds of group III elements by x-ray fluorescence spectroscopy. Communication 1. Charge values at the sulfur atom in arylalkyl and aryl perfluoroalkyl sulfides and sulfones, and at chlorine in their chlorine-substituted derivatives. Russ Chem Bull 36, 296–300 (1987). https://doi.org/10.1007/BF00959367
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DOI: https://doi.org/10.1007/BF00959367