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13C NMR spectroscopy of peroxide derivatives of cyclanes and cyclic peroxides

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The13C NMR spectra of peroxide derivatives of cyclanes and cyclic peroxides have been investigated.

  2. 2.

    Replacement of the exocyclic OH group by OOH for saturated cyclic systems leads to a displacement of the signals from the α-carbon downfield by 13.0 ppm, while the β-carbon is displaced upfield by 4.5 ppm, without any dependence on the size or conformational structure of the rings. Replacement of the transannular 00 group by CH2CH2 or CH2O increases the shielding of the quaternary carbon adjoining it.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. V. Klochkov, V. L. Antonovskii, P. P. Chernov, A. V. Aganov & G. N. Koshel'

  2. V. I. Ul'yanov (Lenin) Kazan State University, USSR

    V. V. Klochkov, V. L. Antonovskii, P. P. Chernov, A. V. Aganov & G. N. Koshel'

Authors
  1. V. V. Klochkov
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  2. V. L. Antonovskii
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  3. P. P. Chernov
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  4. A. V. Aganov
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  5. G. N. Koshel'
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 323–327, February, 1987.

The authors wish to thank E. N. Klimovitskii and D. Yu. Strel'nik for synthesizing compound (XIII) and T. M. Aleinikov for the synthesis of (XII) and (XIV).

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Klochkov, V.V., Antonovskii, V.L., Chernov, P.P. et al. 13C NMR spectroscopy of peroxide derivatives of cyclanes and cyclic peroxides. Russ Chem Bull 36, 285–288 (1987). https://doi.org/10.1007/BF00959364

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  • DOI: https://doi.org/10.1007/BF00959364

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