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Electrochemical chlorination of carbanions

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The general principles of the electrochemical chlorination of polynitrocarbanions of various structures were established, and it was shown that carbanions, more difficult to oxidize than chloride ions, are virtually quantitatively chlorinated on anodes of Pt, graphite, or on an oxide-ruthenium-titanium anode (ORTA).

  2. 2.

    The formation of chloroderivatives of “readily oxidized” carbanions with a high yield is promoted by conducting the process on an ORTA electrode, by high values of the current density, and by high chloride ion concentrations.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. A. Petrosyan, M. E. Niyazymbetov & B. V. Lyalin

Authors
  1. V. A. Petrosyan
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  2. M. E. Niyazymbetov
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  3. B. V. Lyalin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 306–312, February, 1987.

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Petrosyan, V.A., Niyazymbetov, M.E. & Lyalin, B.V. Electrochemical chlorination of carbanions. Russ Chem Bull 36, 269–274 (1987). https://doi.org/10.1007/BF00959361

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  • DOI: https://doi.org/10.1007/BF00959361

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