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Study of the dissolution of metallic copper in the presence of 3,5-di-tert-butyl-1,2-benzoquinone and lithium chloride in tetrahydrofuran

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It was found that the final product of dissolution of metallic copper in a tetrahydrofuran solution of o-quinone in an excess of LiCl is a copper(II) biscatecholate complex.

  2. 2.

    A scale of the electrode potentials characterizing the individual redox stages in the process of dissolution of copper in the conditions studied was elaborated; the scale permits predicting the capacity of copper and its cations and Q,\(SQ^{\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle-}$}}{ \bullet } }\) and Cat2− for mutual redox transformations in tetrahydrofuran.

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the USSR, Gorkii

    G. A. Abakumov, V. K. Cherkasov & Yu. V. Chechet

Authors
  1. G. A. Abakumov
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  2. V. K. Cherkasov
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  3. Yu. V. Chechet
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 292–296, February, 1987.

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Abakumov, G.A., Cherkasov, V.K. & Chechet, Y.V. Study of the dissolution of metallic copper in the presence of 3,5-di-tert-butyl-1,2-benzoquinone and lithium chloride in tetrahydrofuran. Russ Chem Bull 36, 256–260 (1987). https://doi.org/10.1007/BF00959358

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  • DOI: https://doi.org/10.1007/BF00959358

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