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Dehydration of 3-methyl-2-butanol on zeolites

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dehydration of 3-methyl-2-butanol on zeolites Y, mordenite, and entasil in the sodium and hydrogen forms and on dealuminated mordenites was studied. The hydrogen forms of zeolites from the pentasil family and dealuminated mordenite with a SiO2/Al8O3 ratio of 14 exhibit the highest activity.

  2. 2.

    3-Methyl-2-butanol is dehydrated on the zeolites not only according to the mechanism of β-elimination, but also according to the mechanism of γ-eliminatton to a significant degree.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    I. I. Levitskii, A. I. Maksimov, I. V. Mishin & Kh. M. Minachev

Authors
  1. I. I. Levitskii
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  2. A. I. Maksimov
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  3. I. V. Mishin
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  4. Kh. M. Minachev
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 272–277, February, 1987.

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Levitskii, I.I., Maksimov, A.I., Mishin, I.V. et al. Dehydration of 3-methyl-2-butanol on zeolites. Russ Chem Bull 36, 238–242 (1987). https://doi.org/10.1007/BF00959354

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  • DOI: https://doi.org/10.1007/BF00959354

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