Conclusions
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1.
Differences in the catalytic activity of metallocene dichlorides of subgroups IVB-VIB in the amalgam reduction of carbon monoxide are due to thermodynamic factors determining the impossibility of amalgam reduction of the catalyst-substrate complex (subgroup IV) and differences in the stability of the corresponding metallocene (subgroups VB and VIB).
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2.
Amalgam reduction of carbon monoxide, bound in a complex with metallocene, occurs under conditions of transfer of the first electron against the potential gradient.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 258–262, February, 1987.
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Strelets, V.V., Kuzharenko, S.V. & Tsarev, V.N. Causes of the different catalytic activity of metallocene dichlorides of subgroups IVB-VIB in the amalgam reduction of carbon monoxide. Russ Chem Bull 36, 224–228 (1987). https://doi.org/10.1007/BF00959351
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DOI: https://doi.org/10.1007/BF00959351