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Reaction of dichlorocarbene with vinyl sulfides

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reaction of dihalocarbenes with vinyl sulfides gave gem-dihalocyclopropyl sulfides. The relative activity of the sulfides toward dichlorocarbene is 5–6 times greater than that of the corresponding ethers. The theory was expressed that intermediate sulfur ylides are formed in the given reaction.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    R. R. Kostikov, A. P. Molchanov, S. V. Amosova & B. A. Trofimov

  2. A. A. Zhdanov Leningrad State University, USSR

    R. R. Kostikov, A. P. Molchanov, S. V. Amosova & B. A. Trofimov

Authors
  1. R. R. Kostikov
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  2. A. P. Molchanov
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  3. S. V. Amosova
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  4. B. A. Trofimov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1354–1358, June, 1980.

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Kostikov, R.R., Molchanov, A.P., Amosova, S.V. et al. Reaction of dichlorocarbene with vinyl sulfides. Russ Chem Bull 29, 971–975 (1980). https://doi.org/10.1007/BF00958819

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  • DOI: https://doi.org/10.1007/BF00958819

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