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Telomerization of vinyl acetate with methyl esters of propionic and isobutyric acids

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The telomerization of vinyl acetate with methyl isobutyrate leads to the formation of telomers with the structure CH3O2CC(CH3)2[CH2CH(O2CCH3)]nH.

  2. 2.

    In the telomerization of vinyl acetate with methyl propionate, together with the CH3O2CCH(CH3)[CH2-CH(O2CCH3)]nH telomers, are also formed compounds of type CH3O2CCR(CH3)[CH2CH(O2CCH3)]2H due to rearrangement of the radicals with 1,5-H migration.

  3. 3.

    Characteristic signals were isolated in the PMR and13C NMR spectra that permitted reliably establishing the structure of this type of compounds.

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Literature cited

  1. C. M. Starks, Free Radical Telomerization, Academic Press, New York (1974), p. 179.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    M. A. Moskalenko, V. I. Dostovalova & A. B. Terent'ev

Authors
  1. M. A. Moskalenko
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  2. V. I. Dostovalova
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  3. A. B. Terent'ev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1327–1333, June, 1980.

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Moskalenko, M.A., Dostovalova, V.I. & Terent'ev, A.B. Telomerization of vinyl acetate with methyl esters of propionic and isobutyric acids. Russ Chem Bull 29, 948–952 (1980). https://doi.org/10.1007/BF00958814

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  • DOI: https://doi.org/10.1007/BF00958814

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