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NMR study of the dynamic stereochemistry of nitroenamines and of NH exchange

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The kinetically controlled stages of NH exchange and of Z, E-isomerization of the nitroenamines studied have a common transition state that includes a molecule of the reactant and a pyridine molecule.

  2. 2.

    For the enamines studied, a pseudomonomolecular mechanism of NH exchange in an aprotic solvent has been observed.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. I. Bakhmutov, K. A. Kochetkov & É. I. Fedin

Authors
  1. V. I. Bakhmutov
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  2. K. A. Kochetkov
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  3. É. I. Fedin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1295–1301, June, 1980.

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Bakhmutov, V.I., Kochetkov, K.A. & Fedin, É.I. NMR study of the dynamic stereochemistry of nitroenamines and of NH exchange. Russ Chem Bull 29, 916–920 (1980). https://doi.org/10.1007/BF00958807

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  • DOI: https://doi.org/10.1007/BF00958807

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