Summary
In the molecules of symmetrically substituted diarylmethanes, the CAr2 grouping has the C2 symmetry with an orientation of the aryl nuclei close to the eclipsing of the bonds of the central atom.
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D. Gust and K. Mislow, J. Am. Chem. Soc.,95, 1535 (1953).
O. Korver, J. U. Veenland, and T. H. de Boer, Rec. Trav. Chim.,84, 806 (1965).
S. Higuchi, H. Tsuyama, S. Tanaka, and H. Kamada, Spectrochim. Acta, 30A, 463 (1974).
G. Montaudo, S. Cacamese, and P. Finocchiaro, J. Am. Chem. Soc.,93, 4202 (1971).
A. Unanue and P. Bothorel, Bull. Soc. Chim. Fr., 2827 (1965).
M. F. Vuks, The Scattering of Light in Gases, Liquids, and Solutions [in Russian], Izd-vo Leningr. Univ., Leningrad (1977), p. 233.
S. P. Chen and H. H. Huang, J. Chem. Soc. Perkin Trans. 2, 1301 (1972).
E. J. W. Wittaker, Acta Crystallogr.,6, 714 (1953).
V. A. Zubkov, T. M. Birstein, and I. S. Milevskaya, J. Mol. Struct.,27, 139 (1975).
R. E. Calderbank, R. J. W. LeFevre, and R. K. Pierens, J. Chem. Soc., 1115 (1970).
M. J. Aroney, R. J. W. LeFevre, G. L. D. Ritchie, and A. N. Singh, J. Chem. Soc., 5810 (1965).
S. G. Vul'fson, G. Ya. Cheryukanova, G. A. Chmutova, and A. N. Vereshchagin, Dokl. Akad. Nauk SSSR,212, 621 (1973).
R. J. W. LeFevre, Adv. Phys. Org. Chem.,3, 1 (1965).
R. J. W. LeFevre and B. P. Rao, J. Chem. Soc., 3644 (1957).
B. A. Arbuzov, S. G. Vul'fson, I. M. Khamatullina, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR., Ser. Khim., 1332 (1977).
B. A. Arbuzov, S. G. Vul'fson, R. R. Kostikov, L. A. Monetina, A. F. Khlebnikov, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 1300 (1975).
N. N. Tsapkov, Dissertation, Rostov-on-Don (1978).
A. B. Galun, A. Kaluszyner, and E. D. Bergmann, J. Org. Chem.,27, 1426 (1962).
F. Manther, J. Prakt. Chem.,145, 313 (1936).
A. N. Vereshchagin and L. A. Grozina, Teor. Eksp. Khim.,4, 361 (1968).
B. A. Arbuzov, A. N. Vereshchagin, S. G. Vul'fson, in: Collection of Papers on Some Problems of Organic and Physical Chemistry [in Russian], IOFKh AN SSSR, Kazan' (1972), p. 228.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1291–1295, June, 1980.
The authors thank A. M. Salikhova for measuring the IR spectra and A. A. Karelov for assistance in calculating the Kerr constants on the ÉVM-222 computer.
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Arbuzov, B.A., Timosheva, A.P., Vul'fson, S.G. et al. Anisotropy of the polarizability and spatial structure of some diarylmethanes. Russ Chem Bull 29, 912–915 (1980). https://doi.org/10.1007/BF00958806
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DOI: https://doi.org/10.1007/BF00958806