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Telomerization of propylene with methyl acetate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The telomerization of propylene with methyl acetate is accompanied by rearrangement of the first and second growing radicals, with the 1,3- and 1,5-migration of hydrogen.

  2. 2.

    In the telogen series RCH2CO2CH3 (R= CH3, Cl, H), when reaction is with propylene, rearrangement with the 1,3-migration of hydrogen is least in the case of methyl acetate (R =H), which indicates that the R substituent has an important effect on the course of the rearrangement.

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Literature cited

  1. A. B. Terent'ev, N. S. Ikonnikov, V. L. Dostovalova, and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,213, 1345 (1973).

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  2. N. S. Ikonnikov and A. B. Terent'ev, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 371.

  3. A. B. Terent'ev, M. A. Churilova, N. S. Ikonnikov, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 439.

  4. R. Kh. Freidlina and A. B. Terent'ev, Accounts Chem. Res.,10, 9 (1977).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. B. Terent'ev

Authors
  1. A. B. Terent'ev
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2614–2617, November, 1977.

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Terent'ev, A.B. Telomerization of propylene with methyl acetate. Russ Chem Bull 26, 2421–2423 (1977). https://doi.org/10.1007/BF00958747

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  • DOI: https://doi.org/10.1007/BF00958747

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