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Reaction of gold compounds and diazomethane

  • A. N. Nesmeyanov
  • É. G. Perevalova
  • E. I. Smyslova
  • V. P. Dyadchenko
  • K. I. Grandberg
Brief Communications

Conclusions

  1. 1.

    We discovered the reaction of inserting the methylene group at the gold-chlorine bond to give chloromethyl (triphenylphosphine) gold.

     
  2. 2.

    The triphenylphosphine complexes of acetylacetonate-ferrocenyl-, and acetonylgold react with diazomethane to give vinyl(triphenylphosphine) gold.

     
  3. 3.

    The reaction of chloromethyl(triphenylphosphine)gold with KI and NaCN gave, respectively, triphenylphosphinegold iodide and methyltriphenylphosphonium dicyanoaurate.

     

Keywords

Methylene Gold Iodide Vinyl Triphenylphosphine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • A. N. Nesmeyanov
    • 1
  • É. G. Perevalova
    • 1
  • E. I. Smyslova
    • 1
  • V. P. Dyadchenko
    • 1
  • K. I. Grandberg
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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