Conclusions
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1.
The electronic parameters of some hydrazine and nitramine molecules were determined and a comparison was made with the parameters of C-nitro compounds.
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2.
The atomization enthalpies of hydrazines and nitramines are satisfactorily estimated by CNDO/2 calculations using the set of parameters given in [1].
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3.
The enthalpy of the NN bonds is smaller than that of the CN bonds.
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4.
The absolute values of the charges on the atoms of the nitro groups in N-nitro compounds are higher than in C-nitro compounds.
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Literature cited
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2608–2610, November, 1977.
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Belik, A.V., Bakeeva, S.K. & Shlyapochnikov, V.A. Electronic structure of hydrazines and nitramines. Russ Chem Bull 26, 2415–2416 (1977). https://doi.org/10.1007/BF00958744
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DOI: https://doi.org/10.1007/BF00958744