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Solvent effect on dimerization rate of 2, 4, 6-triphenylphenoxyl radicals

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the reversible dimerization rate of the 2,4,6-triphenylphenoxyl radical in various solvents and binary mixtures.

  2. 2.

    It was found that a V-shaped relation exists between the recombination rate constant of the 2, 4, 6-tri-phenylphenoxyl radical and the solvating capacity of the solvents.

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Literature cited

  1. I. V. Khudyakov, K. de Jonge, P. P. Levin, and V. A. Kuz'min, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 444.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    P. P. Levin, I. V. Khudyakov, I. A. Khardina & L. N. Rygalov

Authors
  1. P. P. Levin
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  2. I. V. Khudyakov
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  3. I. A. Khardina
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  4. L. N. Rygalov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2605–2608, November, 1977.

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Levin, P.P., Khudyakov, I.V., Khardina, I.A. et al. Solvent effect on dimerization rate of 2, 4, 6-triphenylphenoxyl radicals. Russ Chem Bull 26, 2412–2415 (1977). https://doi.org/10.1007/BF00958743

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  • DOI: https://doi.org/10.1007/BF00958743

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