Conclusions
Employing the dynamic NMR spectroscopy method it was shown that the Z,E-isomerization ofα-nitro-β-arylaminoacrylic esters in pyridine as the medium is accomplished with prior ionizatioa of the N-H bond.
This is a preview of subscription content, log in via an institution to check access.
Literature cited
Y. Shvo and I. Belsky, Tetrahedron,25, 4643 (1969).
Y. Shvo and H. Shanan-Atidi, J. Am. Chem. Soc.,91, 6683 (1969).
Y. Shvo and H. Shanan-Atidi, J. Am. Chem. Soc.,91, 6689 (1969).
Y. Shvo, E. Taylor, and J. Bartulin, Tetrahedron Lett.,1967, 3259.
H. Kalinowski and H. Kessler, Topics in Stereochemistry,7, 296 (1973).
K. K. Babievskii, V. I. Bakhmutov, K. A. Kochetkov, V. A. Burmistrov, and V. M. Belikov, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 425.
K. K. Babievskii, N. A. Tikhonova, and V. M. Belikov, Izv. Akad. Nauk SSSR, Ser. Khim.,1969, 2755.
M. S. Newman, Steric Effects in Organic Chemistry, J. Wiley and Sons, New York (1956), p. 595.
J. Riddick and W. Bunger, Organic Solvents, J. Wiley and Sons, New York (1970).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2601–2605, November, 1977.
Rights and permissions
About this article
Cite this article
Bakhmutov, V.I., Burmistrov, V.A., Babievskii, K.K. et al. Study of mechanism of Z, E-isomerization of α-nitro-β-arylaminoacrylic esters in solution employing dynamic NMR spectroscopy. Russ Chem Bull 26, 2408–2411 (1977). https://doi.org/10.1007/BF00958742
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00958742