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Reaction of l-methylcyclopropene with methylmagnesium iodide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In contrast to the previously studied cases, 1-methylcyclopropene adds to tbe double bond not only CH3MgI, but also the 1,1-dimethylcyclopropylmagnesium iodide that is formed during reaction.

  2. 2.

    1-(1-methylcyclopropyl)-2,2-dimethylcyclopropane and 2-methyl-cis-1-r -carbomethoxy-2-(2,2-dimethylcyclopropyl)cyclopropane were obtained for the first time.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    O. A. Nesmeyanova, T. Yu. Rudashevskaya & V. I. Grinberg

Authors
  1. O. A. Nesmeyanova
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  2. T. Yu. Rudashevskaya
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  3. V. I. Grinberg
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2590–2592, November, 1977.

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Nesmeyanova, O.A., Rudashevskaya, T.Y. & Grinberg, V.I. Reaction of l-methylcyclopropene with methylmagnesium iodide. Russ Chem Bull 26, 2399–2400 (1977). https://doi.org/10.1007/BF00958738

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  • DOI: https://doi.org/10.1007/BF00958738

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