Conclusions
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1.
IR spectroscopy has been used to study intermolecular and intramolecular hydrogen bonding in certain phosphadepsipeptides.
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2.
In the condensed phase, these compounds associate through the formation of intermolecular hydrogen bonds in a process involving participation of the COOH and NH groups.
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3.
In solution, it is only those compounds which contain open COOH groups which undergo appreciable association; the remaining compounds form intramolecular hydrogen bonds in dilute solution, the bonding process involving NH group participation.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2491–2497, November, 1977.
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Matrosov, E.I., Mastryukova, T.A., Shipov, A.É. et al. Hydrogen bonding and association of certain phosphadepsipeptides. Russ Chem Bull 26, 2310–2314 (1977). https://doi.org/10.1007/BF00958717
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DOI: https://doi.org/10.1007/BF00958717