Catalysts for homogeneous olefin hydrogenation based on macromolecular complexes of transition-metal ions with copolymers of styrene and amino-acid maleimides

  • V. K. Latov
  • V. M. Belikov
  • T. A. Belyaeva
  • A. I. Vinogradova
  • S. D. Soinov
Physical Chemistry
  • 23 Downloads

Conclusions

  1. 1.

    Study of the IR and1H and13C NMR spectra and optical rotary dispersion curves has shown that outer-sphere macromolecular complexes are formed between low-molecular-weight Pd (II) and Rh (III) chloride complexes and copolymers of styrene with amino-acid maleimides.

     
  2. 2.

    The catalytic activity of the outer-sphere complexes in the homogeneous hydrogenation of olefins is due to the formation of active complexes containing the metal in various valence states.

     

Keywords

Hydrogenation Chloride Catalytic Activity Styrene Dispersion Curve 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    E. M. Cernia and M. Graziani, J. Appl. Polym. Sci.,18, 2725 (1975).Google Scholar
  2. 2.
    M. Kraus, Chem. Listy, 66, 1281 (1972).Google Scholar
  3. 3.
    B. R. James, Homogeneous Hydrogenation, Wiley-Interscience (1973).Google Scholar
  4. 4.
    B. K. Latov, V. M. Belikov, K. K. Babievskii, and A. I. Vinogradova, USSR Inventor's Certificate No. 453866, 1974; Byul. Izobr., No. 11, 191 (1976).Google Scholar
  5. 5.
    B. K. Latov and K. K. Babievskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2036 (1972).Google Scholar
  6. 6.
    V. K. Latov, V. M. Belikov, K. K. Babievskii, and A. I. Vinogradova, Izv. Akad. Nauk SSSR, Ser. Khim., 2764 (1973).Google Scholar
  7. 7.
    B. Bosnich, J. Chem. Soc., A, 1394 (1966).Google Scholar
  8. 8.
    J. M. Steward and J. D. Young, Solid-Phase Synthesis of Peptides [Russian translation], Mir (1971), p. 76.Google Scholar
  9. 9.
    P. Pino et al., in: Optical Rotary Dispersion and Circular Dichroism in Organic Chemistry [Russian translation], Mir (1970), p. 333.Google Scholar
  10. 10.
    R. S. Drago, Physical Methods in Inorganic Chemistry, Van Nostrand-Reinhold (1965).Google Scholar
  11. 11.
    G. C. Levy and G. L. Nelson, Carbon-13 Nuclear Magnetic Resonance for Organic Chemists, Wiley-Interscience (1972).Google Scholar
  12. 12.
    R. Ugo, Aspects of Homogeneous Catalysis: A Series of Advances, Reidel Publ. (1970, 1974).Google Scholar
  13. 13.
    R. M. Alcock, F. R. Hartley, D. E. Rogers, and I. L. Wagner, Coord. Chem. Rev.,16, 59 (1975).Google Scholar
  14. 14.
    K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, Wiley-Interscience (1970).Google Scholar

Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • V. K. Latov
    • 1
  • V. M. Belikov
    • 1
  • T. A. Belyaeva
    • 1
  • A. I. Vinogradova
    • 1
  • S. D. Soinov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

Personalised recommendations