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A study of the reactions of alkyl compounds of mercury and group IVb elements with triarylmethane salts by PMR spectroscopy

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The methods of PMR spectroscopy have been used to study the reactions of dipropylmercury, di-n-butylmercury, tetraethyltin, tetrapropyltin, and diisobutylgermanium with triarylmethane salts.

  2. 2.

    Hydride displacement from the metalorganic compound to the triarylmethyl cation proceeds in phase with the breaking of the carbon-metal and β-carbon-hydrogen bonds.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2478–2481, November, 1977.

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Uglova, É.V., Grishin, Y.K. & Reutov, O.A. A study of the reactions of alkyl compounds of mercury and group IVb elements with triarylmethane salts by PMR spectroscopy. Russ Chem Bull 26, 2297–2300 (1977). https://doi.org/10.1007/BF00958714

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  • DOI: https://doi.org/10.1007/BF00958714

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