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The temperature dependence of the rates of branching-chain processes

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It has been shown experimentally that the expression for the temperature dependence of the nonstationary BCP rate contains a term in the exponential Boltzmann factor.

  2. 2.

    The temperature has a marked effect on the rate and evolution of energy in branching-chain processes, i.e., changes in the temperature markedly affect the ratio of relative rates of energy conversion along the various channels.

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Literature cited

  1. N. N. Semenov, Chair Reactions [in Russian], Goskhimtekhizdat, Leningrad (1934); Certain Problems in Chemical Kinetics and Reactivities [in Russian], Izd. Akad. Nauk SSSR (1958).

    Google Scholar 

  2. V. N. Kondrat'ev and E. E. Nikitin, Kinetics and Mechanism of Gas-Phase Reactions [in Russian], Nauka (1974).

  3. N. M. Émanuél' and D. G. Knorre, Course in Chemical Kinetics [in Russian], Vysshaya Shkola (1969).

  4. V. I. Vedeneev, Yu. M. Gershenzon, and O. M. Sarkisov, Dokl. Akad. Nauk SSSR,208, 116 (1973).

    Google Scholar 

  5. V. I. Golovichev, V. I. Dmitriev, and R. I. Soloukhin, Aerophysical Studies [in Russian], Nauka, Novosibirsk (1973), No. 2, p. 13.

    Google Scholar 

  6. V. V. Azatyan, A. M. Kogan, M. G. Neigauz, A. I. Poroikova, and E. N. Aleksandrov, Kinet. Katal.,16, 3 (1975).

    Google Scholar 

  7. V. V. Azatyan, Kinet. Katal.,17, 6, 546 (1976).

    Google Scholar 

  8. V. V. Azatyan and A. A. Shavard, Kinet. Katal.,18, 596 (1977).

    Google Scholar 

  9. N. N. Semenov, Development of a Theory of Chain Reactions and Thermal Explosions [in Russian], Khimiya (1969).

  10. V. V. Azatyan and N. N. Semenov, Kinet. Katal.,13, 17 (1972).

    Google Scholar 

  11. D. L. Baulch, D. D. Drisdale, D. G. Home, and A. C. Lloyd, Evaluated Kinetic Data for High-Temperature Reactions, Vol. 1, Butterworths (1972).

  12. E. N. Aleksandrov and V. V. Azatyan, Dokl. Akad. Nauk SSSR,210, 1358 (1973).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. V. Azatyan & A. A. Shavard

Authors
  1. V. V. Azatyan
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  2. A. A. Shavard
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2460–2463, November, 1977.

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Azatyan, V.V., Shavard, A.A. The temperature dependence of the rates of branching-chain processes. Russ Chem Bull 26, 2279–2283 (1977). https://doi.org/10.1007/BF00958710

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  • DOI: https://doi.org/10.1007/BF00958710

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