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The active forms of palladium in pd-zeolite catalysts for ethylene oligomerization

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

By studying the effects of preliminary treatment of Pd zeolites with various gases and investigating the x-ray photoelectron spectra of the zeolites themselves, it has been shown that it is the cationic form of the metal which is catalytically active in ethylene oligomerization. Metallic Pd is inactive in these catalysts under the conditions of the present work.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. L. Lapidus, V. V. Mal'tsev, E. S. Shpiro, G. V. Antoshin, V. I. Garanin & Kh. M. Minachev

Authors
  1. A. L. Lapidus
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  2. V. V. Mal'tsev
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  3. E. S. Shpiro
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  4. G. V. Antoshin
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  5. V. I. Garanin
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  6. Kh. M. Minachev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2454–2459, November, 1977.

The authors would like to thank V. A. Shvets who obtained the ESR spectrum.

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Lapidus, A.L., Mal'tsev, V.V., Shpiro, E.S. et al. The active forms of palladium in pd-zeolite catalysts for ethylene oligomerization. Russ Chem Bull 26, 2275–2279 (1977). https://doi.org/10.1007/BF00958709

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  • DOI: https://doi.org/10.1007/BF00958709

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