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Pulsed radiolysis of MgO single crystals

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the short-lived absorption spectra of pulse-irradiated MgO single crystals the authors have identified absorption bands belonging to V− centers and manganese impurity ions.

  2. 2.

    The radiation-chemical yields of V− centers in pulse-irradiated specimens are higher than those in gamma-irradiated ones.

  3. 3.

    The authors have studied the kinetics of destruction of color centers in pulse-irradiated MgO single crystals. They have calculated the rate constants and effective activation energies.

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Literature cited

  1. B. Henderson and J. E. Wertz, Adv. Phys.,17, 750 (1968).

    Google Scholar 

  2. A. E. Hughes and B. Henderson, Point Defects in Solids, Vol. 1, General and Ionic Crystals (ed. by J. H. Crawford and Z. M. Slifkin), Plenum Press, New York-London (1972), p. 381.

    Google Scholar 

  3. J. W. Boag, G. W. Dolphin, and J. Rotblat, Radiat. Res.,9, 589 (1958).

    Google Scholar 

  4. A. K. Pikaev, G. K. Sibirskaya, E. M. Shirshov, P. Ya. Glazunov, and V. I. Spitsyn, Dokl. Akad. Nauk SSSR,200, 383 (1971).

    Google Scholar 

  5. J. E. Wertz, G. S. Saville, L. Hall, and P. Auzins, Proc. Brit. Ceram. Soc.,1, 59 (1964).

    Google Scholar 

  6. Y. Chen and W. A. Sibley, Phys. Rev.,154, 842 (1967).

    Google Scholar 

  7. J. E. Wertz, P. Auzins, J. H. E. Griffiths, and J. W. Orton, Disc. Faraday Soc.,28, 136 (1959).

    Google Scholar 

  8. D. L. Dexter, Phys. Rev.,101, 48 (1956).

    Google Scholar 

  9. M. Haase, Z. Kristallogr.,65, 525 (1927).

    Google Scholar 

  10. B. Henderson and R. D. King, Phil. Mag.,13, 1149 (1966).

    Google Scholar 

  11. Y. Chen, W. A. Sibley, F. D. Srygley, R. A. Weeks, E. B. Hensley, and R. L. Kroes, J. Phys. Chem. Solids,29, 863 (1968).

    Google Scholar 

  12. V. I. Spitsyn, G. V. Ionova, L. I. Barsova, and G. Yu. Popova, Izv. Akad. Nauk SSSR, Ser. Khim., 540 (1974).

  13. A. J. Tench and M. J. Duck, J. Phys. C, Solid State Phys.,7, 3981 (1974).

    Google Scholar 

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Author information

Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow

    V. I. Spitsyn, L. I. Barsova & I. I. Zyazyulya

Authors
  1. V. I. Spitsyn
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  2. L. I. Barsova
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  3. I. I. Zyazyulya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2422–2427, November, 1977.

The authors thank S. N. Oziraner for help in the analysis of the impurities in the crystals.

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Spitsyn, V.I., Barsova, L.I. & Zyazyulya, I.I. Pulsed radiolysis of MgO single crystals. Russ Chem Bull 26, 2246–2250 (1977). https://doi.org/10.1007/BF00958703

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  • DOI: https://doi.org/10.1007/BF00958703

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