Skip to main content
SpringerLink
Log in

Synthesis of aluminum hydride complex compounds containing the heptahydridodialuminate anion Al2H7 −

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of alumohydrides of tetraalkylammonium cations with ethereal solutions of A1H3 leads to formation of heptahydridodialuminates of tetraalkylammonium cations, isolated as distinct compounds.

  2. 2

    Complex compounds of NaAlH4 and LiAlH4 with dimethoxyethane form compounds containing the [Al2H7]− anion.

  3. 3.

    Some chemical properties of tetraalkylammonium heptahydridodialuminates have been investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. O. Stecher and E. Wieberg, Ber.75, 2003 (1942).

    Google Scholar 

  2. A. E. Fincholt, A. C. Bond, and H. J. Schlesinger, J. Am. Chem. Soc.,69, 1199 (1947).

    Google Scholar 

  3. USA patent 3819819; Chem. Abstr.,81, 123, 769 (1974); USA patent 3823226; Chem. Abstr.,82, 5719 (1975).

  4. A. E. Fincholt, J. Am. Chem. Soc.,77, 4163 (1955).

    Google Scholar 

  5. L. I. Zakharkin and V. V. Gavrilenko, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 2246 (1961).

  6. L. I. Zakharkin and V. V. Gavrilenko, Izv. Akad. Nauk SSSR, Ser. Khim., 977 (1966).

  7. R. Ehrlih, R. Young, and D. D. Perry, Inorg. Chem.,4, 758 (1965).

    Google Scholar 

  8. V. V. Gavrilenko, Yu. N. Karaksin, and L. I. Zakharkin, Zh. Obshch. Khim.,41, 1511 (1971).

    Google Scholar 

  9. V. V. Gavrilenko, Yu. N. Karaksin, and L. I. Zakharkin, Zh. Obshch. Khim.,42, 1564 (1972).

    Google Scholar 

  10. L. I. Zakharkin and V. V. Gavrilenko, Dokl. Akad. Nauk SSSR,145, 793 (1962).

    Google Scholar 

  11. T. N. Dymova, M. S. Roshchina, S. S. Grazhulene, and V. A. Kuznetsov, Dokl. Akad. Nauk SSSR,184, 1338 (1969).

    Google Scholar 

  12. J. Bousquet, J. Choury, and P. Claudy, Bull. Soc. Chim., France, 3852 (1967).

  13. E. C. Ashby, J. J. Watkins, and H. S. Prasad, Inorg. Chem.,14, 583 (1975).

    Google Scholar 

  14. V. V. Gavrilenko, Yu. N. Karaksin, and L. I. Zakharkin, Izv. Akad. Nauk SSSR, Ser. Khim., 2647 (1970).

  15. S. Hermanek, O. Kriz, J. Plesek, and T. Hanslik, Chem. Ind., 42 (1975).

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. V. Gavrilenko, L. A. Chekulaeva, V. A. Antonovich & L. I. Zakharkin

Authors
  1. V. V. Gavrilenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. A. Chekulaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. A. Antonovich
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. I. Zakharkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2409–2414, November, 1977.

We would like to thank N. A. Grechanaya for obtaining the NMR spectra of 27AI.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gavrilenko, V.V., Chekulaeva, L.A., Antonovich, V.A. et al. Synthesis of aluminum hydride complex compounds containing the heptahydridodialuminate anion Al2H7 − . Russ Chem Bull 26, 2233–2237 (1977). https://doi.org/10.1007/BF00958700

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00958700

Keywords

Search

Navigation