Abstract
The coordination of Rh(PPh3)3Cl on a dicarbaundecaborate polyamide gives a new polymeric rhodium hydride complex with catalytic activity in the hydrosilylation of 1-hexene by triethylsilane. The rhodium derivative of 7,9-dicarbanido-undecaborate(11)-7,9-dicarboxyanilide was synthesized as a model of the monomeric unit. CoIII and NiIV bis(dicarbollyl) complexes also display catalytic activity in hydrosilylation reactions.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 960–962, April, 1991.
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Kats, G.A., Komarova, L.G. & Rusanov, A.L. Synthesis of new polymeric rhodium carborane complexes serving as homogeneous catalysts for the hydrosilylation of 1-hexene. Russ Chem Bull 40, 855–857 (1991). https://doi.org/10.1007/BF00958592
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DOI: https://doi.org/10.1007/BF00958592