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Reactions of diarylamines with hexafluoroacetone

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Diphenylamine reacts with hexafluoroacetone to give a mixture of products, of which 2-(1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)diphenylamine (II) was isolated. N-Arylanthranilic acids modify the 1,1,1,3,3,3-hexafluoro-2-hydroxy-2-propyl group upon the reaction of its sodium salt with the hydrate of hexafluoroacetone (I) under mild conditions. This method gave 4-(1-hydroxy-1-trifluoromethyl-2,2,3-trifluoroethyl)-N-(2,3-xylyl)anthranilic acid from N-(2,3-xylyl)anthranilic acid in 93% yield.

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Literature cited

  1. A. E. Zelenin, N. D. Chkanikov, M. V. Galakhov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 4, 931 (1985).

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  2. USSR Inventor's Certificate No. 799,320; Byull. Izobret., No. 18, 201 (1984).

  3. A. A. Spryskov and L. N. Golubkin, Zh. Obshch. Khim.,31, 901 (1961).

    Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow

    V. D. Sviridov, N. D. Chkanikov, A. F. Kolomiets & A. V. Fokin

Authors
  1. V. D. Sviridov
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  2. N. D. Chkanikov
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  3. A. F. Kolomiets
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  4. A. V. Fokin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 952–954, April, 1991.

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Sviridov, V.D., Chkanikov, N.D., Kolomiets, A.F. et al. Reactions of diarylamines with hexafluoroacetone. Russ Chem Bull 40, 847–849 (1991). https://doi.org/10.1007/BF00958589

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  • DOI: https://doi.org/10.1007/BF00958589

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