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Preparation of silyl derivatives of unsaturated carbocyclic compounds by the Diels-Alder reaction of 1,2-dimethylenecyclobutane and vinylsilanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The Diels-Alder reactions of 1,2-dimethylenecyclobutane with vinyltrichlorosilane and vinylmethyldichlorosilane give the corresponding trichlorosilyl and methyldichlorosilyl derivatives of cyclobutene. Methylation of these derivatives gave 4-trimethylsilylbicyclo[4.2.0]oct-1-ene, which underwent thermal isomerization to 4-trimethylsilyl-1,2-dimethylcyclohexane.

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Literature cited

  1. S. P. Chernykh, A. M. Taber, A. I. Rudenkov, et al. Neftepererab. Neftekhim, No. 7, 48 (1981).

    Google Scholar 

  2. S. P. Chernykh, A. I. Rudenkov, I. V. Kalechits, et al., Khim. Promyshl., No. 6, 335–336 (1982).

    Google Scholar 

  3. H. G. Kuivila and C. R. Warnes, J. Org. Chem.,29, No. 10, 2845 (1964).

    Google Scholar 

  4. R. F. Cunico, J. Org. Chem.,36, No. 7, 229 (1971).

    Google Scholar 

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    N. V. Ushakov, G. V. Bakulina, A. V. Patrikeev, E. B. Portnykh, V. D. Oppengeim & E. Sh. Finkel'shtein

Authors
  1. N. V. Ushakov
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  2. G. V. Bakulina
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  3. A. V. Patrikeev
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  4. E. B. Portnykh
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  5. V. D. Oppengeim
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  6. E. Sh. Finkel'shtein
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 943–945, April, 1991.

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Ushakov, N.V., Bakulina, G.V., Patrikeev, A.V. et al. Preparation of silyl derivatives of unsaturated carbocyclic compounds by the Diels-Alder reaction of 1,2-dimethylenecyclobutane and vinylsilanes. Russ Chem Bull 40, 838–841 (1991). https://doi.org/10.1007/BF00958585

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  • DOI: https://doi.org/10.1007/BF00958585

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