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Photoelectron spectra of vinyl tellurides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The lowest energy band in the photoelectron (PE) spectra of alkyl vinyl tellurides is attributed toπ-MO with predominant contribution from the pz-AO of the tellurium atom. The second and fourth lowest energy bands correspond toσ-MO. An additionalπ-MO is located between theseσ-MO. The introduction of a second vinyl group hardly affects the HOMO. The heterocyclization of divinyl telluride has a large perturbation effect. Nevertheless, divinyl telluride and tellurophene have the same type of orbital structure.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    L. M. Sinegovskaya, A. A. Tatarinova, N. K. Gusarova & B. A. Trofimov

Authors
  1. L. M. Sinegovskaya
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  2. A. A. Tatarinova
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  3. N. K. Gusarova
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  4. B. A. Trofimov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 935–939, April, 1991.

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Sinegovskaya, L.M., Tatarinova, A.A., Gusarova, N.K. et al. Photoelectron spectra of vinyl tellurides. Russ Chem Bull 40, 831–834 (1991). https://doi.org/10.1007/BF00958583

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  • DOI: https://doi.org/10.1007/BF00958583

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