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Reaction of styrene with sulfur and triiron dodecacarbonyl and the molecular structure of the complex Fe2(CO)6(SCH2S)

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Reaction of excess styrene with Fe3(CO)12 and sulfur (60°C, 15 h, Ar, S/Fe3(CO)12 0.6 g-atom/mole) gave Fe2(CO)6S2, Fe3(CO)9S2, Fe2(CO)6(S2CO), Fe2(CO)6S2(PhCHCH2), PhCHCH2S4, and a novel binuclear complex Fe2(CO)6(S2CH2S), whose structure was analyzed by x-ray crystallography. The crystals are monoclinic, a=7.764(3), b=13.205(4), c=6.628(6) Å, β=98.97(3)°. V=671.2(7) Å3, Z=2, space group P21/m. The bond lengths are Fe-Fe 2.520(2), Fe-S 2.236(2), S-S 2.078(4), C-S 1.825(12), Fe-CO 1.784(8), and C≡O 1.148(9) Å.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    A. I. Nekhaev, B. I. Kolobkov, M. T. Toshev, Kh. B. Dustov & G. G. Aleksandrov

  2. Technological Institute of Food and Light Industry, Bukhara

    A. I. Nekhaev, B. I. Kolobkov, M. T. Toshev, Kh. B. Dustov & G. G. Aleksandrov

  3. All-Union Scientific Reasearch Institute of Antibiotics, Moscow

    A. I. Nekhaev, B. I. Kolobkov, M. T. Toshev, Kh. B. Dustov & G. G. Aleksandrov

Authors
  1. A. I. Nekhaev
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  2. B. I. Kolobkov
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  3. M. T. Toshev
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  4. Kh. B. Dustov
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  5. G. G. Aleksandrov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 930–934, April, 1991.

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Nekhaev, A.I., Kolobkov, B.I., Toshev, M.T. et al. Reaction of styrene with sulfur and triiron dodecacarbonyl and the molecular structure of the complex Fe2(CO)6(SCH2S). Russ Chem Bull 40, 827–830 (1991). https://doi.org/10.1007/BF00958582

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  • DOI: https://doi.org/10.1007/BF00958582

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