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Chlorine and hydrogen transfer by metal carbonyl intermediates

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The reduction of 1,1,1,5-tetrachloropentane by toluene in the presence of the Fe(CO)5 or M(CO)6 (M=Cr, Mo, W) in conjunction with triphenylphosphine was investigated. It was shown that the chlorine-containing metal carbonyl intermediates formed in the process take part in the transfer of the chlorine atom to the benzyl radicals. It was shown that HMn(CO)5 is not the main intermediate responsible for the transfer of hydrogen by the chloroalkyl radicals, which are formed during the reduction of 1,3,3,5-tetrachloropentane by triethylsilane in the presence of Mn2(CO)10.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. V. Il'inskaya, V. F. Kuznetsov & R. G. Gasanov

Authors
  1. L. V. Il'inskaya
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  2. V. F. Kuznetsov
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  3. R. G. Gasanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 927–930, April, 1991.

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Il'inskaya, L.V., Kuznetsov, V.F. & Gasanov, R.G. Chlorine and hydrogen transfer by metal carbonyl intermediates. Russ Chem Bull 40, 823–826 (1991). https://doi.org/10.1007/BF00958581

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  • DOI: https://doi.org/10.1007/BF00958581

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