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Cyclization of some linear terpenols initiated by “activated” DMSO

  • A. A. Surkova
  • A. V. Lozanova
  • V. A. Dragan
  • V. A. Gur'yan
  • A. M. Moiseenkov
Organic Chemistry
  • 51 Downloads

Abstract

It was shown that the acylhydroxysulfonium salt generated in situ from DMSO and trifluoroacetic anhydride causes low-temperature cyclization of geraniol, linalool, and nerol in an aprotic medium to a mixture of p-menthane monoterpenoids, and the maximum yield is obtained in the case of the last two terpenols. A similar result was obtained for E-nerolidol.

Keywords

DMSO Anhydride Maximum Yield Linalool Geraniol 
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Copyright information

© Plenum Publishing Corporation 1991

Authors and Affiliations

  • A. A. Surkova
    • 1
  • A. V. Lozanova
    • 1
  • V. A. Dragan
    • 1
  • V. A. Gur'yan
    • 1
  • A. M. Moiseenkov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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