Abstract
The synthesis of 1-vinyl-1-methyl-3-chloromethylcyclohex-3-ene from 3-vinyl-3-methylcyclohexanone and the corresponding exomethylene derivative has been optimized and related allylsulfones prepared. By a standard combination of these compounds with the appropriate (cyclo)geranyl block synthones a series of regular functionalized diterpenoids has been prepared which are considered as likely precursors of the natural compounds indicated in the title.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 857–862, April, 1991.
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Dragan, V.A., Veselovskii, V.V., Daeva, E.D. et al. 3-Substituted 1-vinyl-1-methylcyclohex-3-enes — Precursors of tricyclic diterpenoids of the pimarane/rosane group. Russ Chem Bull 40, 754–759 (1991). https://doi.org/10.1007/BF00958567
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DOI: https://doi.org/10.1007/BF00958567