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Effective synthesis of 7-ketonor-α-geraniol, 7-ketonor-α-nerol, and 6,8-dioxabicyclooctanes from them

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

A simple synthesis of 7-ketonor-α-nerol and -geraniol has been developed. It was shown that epoxidation of these allyl alcohols or the silyl ether of the latter proceeds stereospecifically, possibly via the stage of the corresponding unstable epoxides, and results in the formation of derivatives of 6,8-dioxabicyclo[3,2,1]octane.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. V. Belyankin, V. V. Veselovskii, A. S. Shashkov & A. M. Moiseenkov

Authors
  1. A. V. Belyankin
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  2. V. V. Veselovskii
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  3. A. S. Shashkov
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  4. A. M. Moiseenkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 846–852, April, 1991.

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Belyankin, A.V., Veselovskii, V.V., Shashkov, A.S. et al. Effective synthesis of 7-ketonor-α-geraniol, 7-ketonor-α-nerol, and 6,8-dioxabicyclooctanes from them. Russ Chem Bull 40, 743–749 (1991). https://doi.org/10.1007/BF00958565

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  • DOI: https://doi.org/10.1007/BF00958565

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