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A new ligand, BEDT-TTF: crystal and molecular structure of (BEDT-TTF)Cu3I4

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

X-ray structural examination of (BEDT-TTF)Cu3I4 crystals has shown for the first time that BEDT-TTF, previously known solely as a neutral molecule or cation-radical, acts as a bidentate ligand in binding Cu atoms.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    S. V. Konovalikhin, O. A. D'yachenko, A. B. Zolotoi, V. V. Gritsenko, L. O. Atovmyan & E. É. Laukhina

Authors
  1. S. V. Konovalikhin
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  2. O. A. D'yachenko
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  3. A. B. Zolotoi
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  4. V. V. Gritsenko
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  5. L. O. Atovmyan
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  6. E. É. Laukhina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 811–816, April, 1991.

The authors are grateful to Yu. M. Shul'g and V. I. Krinichnyi for measurements of the x-ray photoelectron and EPR spectra and to É. B. Yagubskii for discussions of the results.

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Konovalikhin, S.V., D'yachenko, O.A., Zolotoi, A.B. et al. A new ligand, BEDT-TTF: crystal and molecular structure of (BEDT-TTF)Cu3I4 . Russ Chem Bull 40, 711–715 (1991). https://doi.org/10.1007/BF00958559

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  • DOI: https://doi.org/10.1007/BF00958559

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