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Topomerization of substituted 1-amino- and 1-oxy-Δ2-1,2,3-triazolines

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

For 1-amino- and 1-oxy-Δ2-1,2,3-triazolines, retardation (on the NMR time scale) is observed for rotation around the exocyclic N-N or N-O bond; the measured barriers to topomerization amount to 8.3–13.8 kcal/mole.

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    N. L. Zaichenko, G. V. Shustov, A. V. Prosyanik, P. N. Belov, G. K. Kadorkina & R. G. Kostyanovskii

Authors
  1. N. L. Zaichenko
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  2. G. V. Shustov
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  3. A. V. Prosyanik
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  4. P. N. Belov
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  5. G. K. Kadorkina
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  6. R. G. Kostyanovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 790–794, April, 1991.

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Zaichenko, N.L., Shustov, G.V., Prosyanik, A.V. et al. Topomerization of substituted 1-amino- and 1-oxy-Δ2-1,2,3-triazolines. Russ Chem Bull 40, 692–696 (1991). https://doi.org/10.1007/BF00958556

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  • DOI: https://doi.org/10.1007/BF00958556

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