Radical arylation of acetyl-substituted thioureas
- 22 Downloads
The reaction of N-acetylthiourea with phenyl and p-tolyl radicals leads to diaryl disulfides and 2-methyl -4-thioaryl-6-acetamido-s-triazines.
A scheme was proposed for the formation of substituted s-triazines by the successive transformation of the intermediate radicals.
KeywordsPhenyl Disulfide Thiourea Intermediate Radical Radical Arylation
Unable to display preview. Download preview PDF.
- 1.B. V. Kopylova, I. I. Kondror, and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,243, 1147 (1978).Google Scholar
- 2.L. V. Yashkina, B. V. Kopylova, R. G. Gasanov, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim.,1982, 460.Google Scholar
- 3.R. Hoffmann, Mechanisms of Chemical Reactions [Russian translation], Khimiya, Moscow (1979), p. 206.Google Scholar
- 4.G. C. Levy and G. L. Nelson,13C Nuclear Magnetic Resonance for Organic Chemists, Wiley (1972).Google Scholar