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Radical arylation of acetyl-substituted thioureas

  • L. V. Yashkina
  • B. V. Kopylova
  • V. I. Dostovalova
  • B. Kh. Freidlina
Brief Communications
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Conclusions

The reaction of N-acetylthiourea with phenyl and p-tolyl radicals leads to diaryl disulfides and 2-methyl -4-thioaryl-6-acetamido-s-triazines.

A scheme was proposed for the formation of substituted s-triazines by the successive transformation of the intermediate radicals.

Keywords

Phenyl Disulfide Thiourea Intermediate Radical Radical Arylation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    B. V. Kopylova, I. I. Kondror, and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,243, 1147 (1978).Google Scholar
  2. 2.
    L. V. Yashkina, B. V. Kopylova, R. G. Gasanov, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim.,1982, 460.Google Scholar
  3. 3.
    R. Hoffmann, Mechanisms of Chemical Reactions [Russian translation], Khimiya, Moscow (1979), p. 206.Google Scholar
  4. 4.
    G. C. Levy and G. L. Nelson,13C Nuclear Magnetic Resonance for Organic Chemists, Wiley (1972).Google Scholar

Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • L. V. Yashkina
    • 1
  • B. V. Kopylova
    • 1
  • V. I. Dostovalova
    • 1
  • B. Kh. Freidlina
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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