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Reaction of bis(hydroxymethyl)phenylphosphine with dimethylformamide dimethylacetal

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of bis(hydroxymethyl)phenylphosphine with dimethylformamide dimethylacetal gave 2-dimethylamino-5-phenyl-1,3,5-dioxaphosphorinane as the major product and dimethylaminomethylenephenylphosphine. The reaction of phenylphosphine and bis(dimethylamino)methoxymethane is indicated for the preparation of dimethylaminomethylenephenylphosphine.

  2. 2.

    Dimethylaminomethylenephenylphosphine adds tetrachlorocyclopentadienone dimethylacetal at room temperature to give 1,4,5,6-tetrachloro-7,7-dimethoxy-3-dimethylamino-2-phenyl-2-phospha-5-norbornene in quantitative yield.

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Literature cited

  1. B. A. Arbuzov, O. A. Erastov, and A. S. Ionkin, Izv. Akad. Nauk SSSR, Ser. Khim., 418 (1986).

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    A. S. Ionkin, O. A. Erastov & B. A. Arbuzov

Authors
  1. A. S. Ionkin
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  2. O. A. Erastov
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  3. B. A. Arbuzov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2116–2118, September, 1987.

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Ionkin, A.S., Erastov, O.A. & Arbuzov, B.A. Reaction of bis(hydroxymethyl)phenylphosphine with dimethylformamide dimethylacetal. Russ Chem Bull 36, 1967–1969 (1987). https://doi.org/10.1007/BF00958361

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  • DOI: https://doi.org/10.1007/BF00958361

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