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Hydrolysis of 2-acetyl-substituted fluoroalkyl 3-ketoesters

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Fluoroalkyl 2-acetyl-3-ketoesters are hydrolyzed by a) aqueous KOH regioselectively with cleavage of the C2-C3 bond, b) aqueous ethanolic KOH and aqueous pyridine with cleavage of the C2-C3 and C2-C4 bonds, and c) in neutral aqueous and acid media with cleavage of the C1-C2 and C2-C4 bonds.

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Authors and Affiliations

  1. Institute of Chemistry, Urals Science Center, Academy of Sciences of the USSR, Sverdlovsk

    V. M. Krokhalev, V. I. Saloutin & K. I. Pashkevich

Authors
  1. V. M. Krokhalev
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  2. V. I. Saloutin
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  3. K. I. Pashkevich
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2112–2113, September, 1987.

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Krokhalev, V.M., Saloutin, V.I. & Pashkevich, K.I. Hydrolysis of 2-acetyl-substituted fluoroalkyl 3-ketoesters. Russ Chem Bull 36, 1962–1964 (1987). https://doi.org/10.1007/BF00958359

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  • DOI: https://doi.org/10.1007/BF00958359

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