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Mechanism for the inhibition of the autooxidation of cyclohexanone by alkylammonium salts

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Tetraalkylammonium salts may efficiently hinder the oxidation of ketones by catalyzing the decomposition of α-ketohydroperoxides, mainly through a pathway not involving the formation of free radicals.

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Literature cited

  1. K. Fukui, K. Ohkubo, and T. Yamabe, Bull. Chem. Soc., Jpn.,42, 312 (1969).

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  2. L. V. Petrov, V. M. Solyanikov, and E. T. Denisov, Izv. Akad. Nauk SSSR, Ser. Khim., 739 (1977).

  3. L. V. Petrov, Chemical Sciences Candidate's Dissertation [in Russian], Chernogolovka (1978).

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Authors and Affiliations

  1. Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    L. V. Petrov, M. P. Dukh & V. M. Solyanikov

Authors
  1. L. V. Petrov
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  2. M. P. Dukh
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  3. V. M. Solyanikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2100–2102, September, 1987.

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Petrov, L.V., Dukh, M.P. & Solyanikov, V.M. Mechanism for the inhibition of the autooxidation of cyclohexanone by alkylammonium salts. Russ Chem Bull 36, 1951–1953 (1987). https://doi.org/10.1007/BF00958355

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  • DOI: https://doi.org/10.1007/BF00958355

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