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Calorimetric study of the reaction of cellulose with mixtures of nitric acid and methane derivatives

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was carried out on the effect of chloro and nitro derivatives of methane on the nature and quantitative indices of the nitration of cellulose by nitric acid.

  2. 2.

    The use of mixtures of HNO3 and an organic solvent gives rapid nitration of cellulose as a consequence both of the high rate of diffusion of these mixtures into the interior of the cellulose fiber and with structural transformations during nitration.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    N. V. Novikova, Yu. N. Matyushin, V. F. Sopin, G. L. Ryzhova & Yu. A. Lebedev

  2. V. V. Kuibyshev Tomsk State University, USSR

    N. V. Novikova, Yu. N. Matyushin, V. F. Sopin, G. L. Ryzhova & Yu. A. Lebedev

Authors
  1. N. V. Novikova
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  2. Yu. N. Matyushin
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  3. V. F. Sopin
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  4. G. L. Ryzhova
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  5. Yu. A. Lebedev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2095–2098, September, 1987.

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Novikova, N.V., Matyushin, Y.N., Sopin, V.F. et al. Calorimetric study of the reaction of cellulose with mixtures of nitric acid and methane derivatives. Russ Chem Bull 36, 1947–1949 (1987). https://doi.org/10.1007/BF00958353

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  • DOI: https://doi.org/10.1007/BF00958353

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