Cyclohexa-1,3-diene in the synthesis of η4-diene, η5-dienyl, and η6-arene derivatives of platinum metals

  • A. A. Bezrukova
  • V. S. Khandkarova
  • V. G. Andrianov
  • Yu. T. Struchkov
  • A. Z. Rubezhov
Organic Chemistry

Conclusions

  1. 1.

    An efficient method has been developed for the preparation of η4-diene, η5-dienyl, and η6-arene complexes of Ir, Os, and Ru, starting with 1,3-cyclohexadiene and the corresponding platinum metal salts.

     
  2. 2.

    Treatment of 1,3-cyclohexadiene with Na2OsCl6 in the presence of SnCl2 results in the formation of η4-cyclohexadiene-η5-cyclohexadienyl(trichlorostannyl)osmium, which is a rare example of an organic π-complex containing an Os-Sn bond.

     

Keywords

Platinum Diene Osmium Efficient Method Metal Salt 

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Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • A. A. Bezrukova
    • 1
  • V. S. Khandkarova
    • 1
  • V. G. Andrianov
    • 1
  • Yu. T. Struchkov
    • 1
  • A. Z. Rubezhov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Organometallic CompoundsAcademy of Sciences of the USSRMoscow

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