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Reactions of 2,4-dimethylphenylmercury and pentamethylphenylmercury acetates with olefins in the presence of Pd(II) and Pt(IV) complexes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    2,4-Dimethylphenylmercury acetate arylates styrene in the presence of chloro complexes of Pd(II) and Pt(IV), but pentamethylphenylmercury acetate forms with styrene the corresponding substituted stilbene only in the presence of PdCl3 −, and only the free arene is formed in the presence of PtCl6 2−.

  2. 2.

    In the presence of Pd(II) or Pt(IV) complexes the trans-stilbene is not arylated by pentamethylphenylmercury acetate.

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Literature cited

  1. I. V. Kozhevnikov, Usp. Khim.,47, 1231 (1978).

    Google Scholar 

  2. O. A. Reutov, I. P. Beletskaya, G. A. Artamkina, and A. N. Kashin, Reactions of Organometallic Compounds as Redox Processes [in Russian], Nauka, Moscow (1981), pp. 144–146.

    Google Scholar 

  3. R. F. Heck, J. Am. Chem. Soc.,90, 5542 (1968);91, 6707 (1969);93, 6896 (1971).

    Google Scholar 

  4. G. V. Nizova and G. B. Shul'pin, Izv. Akad. Nauk SSSR, Ser, Khim., 2653 (1981).

  5. G. V. Nizova and G. B. Shul'pin, Izv. Akad. Nauk SSSR, Ser. Khim., 2374 (1986).

  6. G. V. Nizova, P. Lederer, and G. B. Shul'pin, Oxid. Commun.,4, 131 (1983).

    Google Scholar 

  7. G. B. Shul'pin and G. V. Nizova, J. Organomet. Chem.,276, 109 (1984).

    Google Scholar 

  8. G. B. Shul'pin, Zh. Obshch. Khim.,50, 2628 (1980).

    Google Scholar 

  9. R. F. Heck, J. Am. Chem. Soc.,90, 5518 (1968).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    G. V. Nizova & G. B. Shul'pin

Authors
  1. G. V. Nizova
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  2. G. B. Shul'pin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2070–2071, September, 1987.

The authors thank V. I. Sokolov for valuable advice.

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Nizova, G.V., Shul'pin, G.B. Reactions of 2,4-dimethylphenylmercury and pentamethylphenylmercury acetates with olefins in the presence of Pd(II) and Pt(IV) complexes. Russ Chem Bull 36, 1920–1921 (1987). https://doi.org/10.1007/BF00958346

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  • DOI: https://doi.org/10.1007/BF00958346

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