Conclusions
-
1.
We observed rearrangement of the σ-vinylphosphonium ligand to a π-olefin phosphonium ligand, occurring in the coordination sphere of the manganese under the action of protic acids.
-
2.
By the x-ray diffraction analysis method we established the structure of [Cp(CO)2Mn (π-PhHC=CHP+Ph3)]Cl−.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
N. E. Kolobova, L. L. Ivanov, O. S. Zhvanko et al., J. Organometal. Chem.,265, 271 (1984).
N. E. Kolobova, O. M. Khitrova, and L. L. Ivanov, Izv. Akad. Nauk SSSR, Ser. Khim., 1436 (1984).
N. E. Kolobova, O. M. Khitrova, and L. L. Ivanov, Izv. Akad. Nauk SSSR, Ser. Khim., 188 (1986).
A. B. Antonova, S. V. Kovalenko, E. D. Korniyets et al., J. Organometal. Chem.,244, 35 (1983).
R. G. Gerr, A. I. Yanovskii, and Yu. T. Struchkov, Kristallografiya,28, 1029 (1983).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2057–2060, September, 1987.
Rights and permissions
About this article
Cite this article
Kolobova, N.E., Khitrova, O.M., Batsanov, A.S. et al. σ-π Rearrangement of vinylphosphonium ligand in the coordination sphere of manganese, the crystal and molecular structure of [η5-C5H5(CO)2Mn(η2-PhHc=CHP+Ph3]Cl− . Russ Chem Bull 36, 1908–1910 (1987). https://doi.org/10.1007/BF00958343
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00958343